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Ammu , Mathew and Abdul , Jaleel (2014) Supramolecular Functionalization and Concomitant Enhancement in Properties of Au25 Clusters. ACS nano, 8 (1). pp. 139-152. ISSN 1936-086X

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Abstract

We present a versatile approach for tuning the surface functionality of an atomically precise 25 atom gold cluster using specific host�guest interactions between β-cyclodextrin (CD) and the ligand anchored on the cluster. The supramolecular interaction between the Au25 cluster protected by 4-(t-butyl)benzyl mercaptan, labeled Au25SBB18, and CD yielding Au25SBB18∩CDn (n = 1, 2, 3, and 4) has been probed experimentally using various spectroscopic techniques and was further analyzed by density functional theory calculations and molecular modeling. The viability of our method in modifying the properties of differently functionalized Au25 clusters is demonstrated. Besides modifying their optoelectronic properties, the CD moieties present on the cluster surface provide enhanced stability and optical responses which are crucial in view of the potential applications of these systems. Here, the CD molecules act as an umbrella which protects the fragile cluster core from the direct interaction with many destabilizing agents such as metal ions, ligands, and so on. Apart from the inherent biocompatibility of the CD-protected Au clusters, additional capabilities acquired by the supramolecular functionalization make such modified clusters preferred materials for applications, including those in biology.

Item Type: Article
Uncontrolled Keywords: Au25; cyclodextrin; inclusion complex; quantum clusters; supramolecular chemistry
Subjects: Cardiovascular Diseases And Diabetes Biology
Depositing User: Rgcb Library
Date Deposited: 14 Jul 2017 08:10
Last Modified: 22 Jun 2018 08:00
URI: http://rgcb.sciencecentral.in/id/eprint/404

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