Anto , P. L. and Anto, R. J. (2009) FT‐IR, FT‐Raman and SERS spectra of anilinium sulfate. J. Raman Spectrosc, 40 (12). pp. 1810-1815. ISSN 1097-4555

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Abstract

The FT‐IR and FT‐Raman spectra of anilinium sulfate were recorded and analyzed. The surface‐enhanced Raman scattering (SERS) was recorded from a silver electrode. The vibrational wavenumbers of the compound have been computed using the Hartree‐Fock/6‐31G* basis and compared with the experimental values. The molecule is adsorbed on the silver surface with the benzene ring in a tilted orientation. The presence of amino and sulfate group vibrations in the SERS spectrum reveal the interaction between amino and sulfate groups with the silver surface. The direction of the charge transfer contribution to SERS has been discussed from the frontier orbital theory. Copyright © 2009 John Wiley & Sons, Ltd.

Item Type:	Article
Uncontrolled Keywords:	anilinium sulfate; FT-IR spectra; FT-Raman spectra; SERS; Hartree-Fock ab initio calculations
Subjects:	Cancer Research
Depositing User:	Central Library RGCB
Date Deposited:	25 Sep 2019 06:26
Last Modified:	25 Sep 2019 06:26
URI:	http://rgcb.sciencecentral.in/id/eprint/877

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